Comments on: The Big Damn Post Of Carbohydrate-Related Chemistry Definitions https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/ Mon, 19 Sep 2022 07:51:56 +0000 hourly 1 https://wordpress.org/?v=6.6.2 By: James Ashenhurst https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-634561 Wed, 03 Aug 2022 20:30:07 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-634561 In reply to Ayesha Aslam.

In general the alpha anomer in pyranoses tends to be more stable due to the anomeric effect, but there is significant solvent dependence.

]]> By: What Is The Anomeric Carbon In Sucrose? Top Answer Update - Ecurrencythailand.com https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-632668 Mon, 11 Jul 2022 05:02:43 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-632668 […] + View Here […]

]]> By: Ayesha Aslam https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-620610 Mon, 14 Feb 2022 12:22:22 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-620610 Which pyran structure would you say is more stable? Alpha or beta?

]]> By: Karan https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-606110 Sun, 03 Oct 2021 04:03:01 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-606110 The anomeric carbon has a property known as the anomalous effect, which is a preference for an electronegative one for an axial orientation over an equatorial orientation. This explanation also included carbohydrates, the cyclic system, and the saturated heterocycle. It is known that in the odd case the electronegative one exists as an axial performer.
https://science-hub.tech/anomeric-carbon-identification-of-the-anomeric/

]]> By: James Ashenhurst https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-558661 Tue, 23 Jul 2019 11:30:42 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-558661 In reply to Max D.

Thank you so much for catching that! Fixed.

]]> By: Max D https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-558646 Tue, 23 Jul 2019 05:49:52 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-558646 “Pyranose – a six-membered cyclic hemiacetal. Derived from the name pyran, a five membered cylic ether.”

Believe it should say pyran is a 6 membered cyclic ether. Notice cyclic is also misspelled.

]]> By: James Ashenhurst https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-548028 Wed, 20 Feb 2019 20:39:36 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-548028 In reply to Chris G..

There’s a huge difference between the structure of something like mannitol and the structure of stevia and aspartame. Those aren’t carbohydrates, and don’t belong here.

]]> By: Chris G. https://www.masterorganicchemistry.com/2018/02/19/the-big-damn-post-of-sugar-nomenclature/#comment-528533 Wed, 28 Feb 2018 01:24:59 +0000 https://www.masterorganicchemistry.com/?p=11367#comment-528533 I know you included alditol but why not categorize it under “sugar alcohols” and also include common alcohols such as isomalt, aspartame, and stevia?

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