Comments on: Geometric Isomers In Small Rings: Cis And Trans Cycloalkanes https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/ Thu, 07 Dec 2023 21:59:38 +0000 hourly 1 https://wordpress.org/?v=6.6.2 By: Geometric Isomers In Small Rings: Cis And Trans Cycloalkanes | Straight A Mindset https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-679032 Thu, 07 Dec 2023 21:59:38 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-679032 […] Cycloalkanes And Constitutional Isomers […]

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By: James Ashenhurst https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-634611 Thu, 04 Aug 2022 18:36:43 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-634611 In reply to Memeber.

Fixed. Thank you!

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By: Memeber https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-631699 Fri, 01 Jul 2022 20:35:31 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-631699 The diagrams should be flipped (the constitutional isomer one belongs where the geometric isomer one is, and vice versa).

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By: Sourav Pathak https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-560771 Fri, 16 Aug 2019 11:26:40 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-560771 Will trans-cyclohexane-1,3-diol show optical activity?

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By: James Ashenhurst https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-558722 Wed, 24 Jul 2019 12:16:39 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-558722 In reply to Tanmay.

That’s a great exercise for you to work on! Start by drawing cyclobutane, and then making all the chlorines “wedges” (or dashes, you’ll get the same thing). Then, systematically “flip” the dashes into wedges and compare to see if they are different isomers.

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By: Tanmay https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-558714 Wed, 24 Jul 2019 07:46:50 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-558714 How many geometrical isomers of 1,2,3,4 tetrachlrocyclobutane is possible?

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By: James https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-529252 Mon, 12 Mar 2018 21:38:08 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-529252 In reply to Muttalib Sheriff.

A cyclohexane ring is *configurationally* locked. Meaning that groups can’t flip on to the other *face* of the ring. i.e. we can’t do a ring flip to convert (for example) cis-1,2-dimethylcyclohexane to trans-1,2-dimethylcyclohexane. A “ring flip” just interconverts which groups are axial and which are equatorial.

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By: Muttalib Sheriff https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-529013 Thu, 08 Mar 2018 09:25:29 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-529013 In the YouTube video you mentioned at the beginning, you say that cyclohexane is conformationally locked. Then how does it undergo ring flip.

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By: Some Study Techniques | Organic Chemistry https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-308313 Sat, 04 Oct 2014 07:46:44 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-308313 […] Post about Isomers (bonus cat references) […]

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By: Bredt’s Rule (And Summary of Cycloalkanes) — Master Organic Chemistry https://www.masterorganicchemistry.com/2014/03/20/cycloalkanes-cis-and-trans/#comment-280911 Tue, 02 Sep 2014 20:12:36 +0000 https://www.masterorganicchemistry.com/?p=8047#comment-280911 […] Rings of size <8 cannot turn inside-out, meaning that configurations of substituents relative to each other are locked. The simple way to say this is that it leads to the existence of cis and trans isomers for the disubstituted cases ( sometimes called “geometric isomers”) – e.g. cis- and trans- 1,2-dimethylcyclohexane. […]

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